Hi Txxxrho
I don't know anything about vitamins in the context of mental health issues.
However, a while ago I was a member of a therapy group for people with mood disorders (Major Depressive Disorder in my case). Another member of the group had severe Generalised Anxiety Disorder.
She found that a combination of learning mindfulness/meditation methods, breathing exercises and Cognitive Behavioural Therapy was highly effective for her GAD. She refers to those things as her "toolkit".
Sometimes I run into her at the local coffee shop - she is completely recovered
.
It might help if you found a mental health professional who has experience of using those approaches when working with his/her clients.
All the best.